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HomeMy WebLinkAboutSDS - Nickel Alloy - ATISAFETY DATA SHEET Issue Date 28-May-2015 Revision Date 03-Aug-2018 Version 6 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Nickel-Base Alloys Other means of identification Product Code SM001 Synonyms Non-powder forms of A905L™ Alloy, ATI 10242™ Alloy, ATI 120™ Alloy, Rene 88DT, ATI 188™ Alloy, ATI 200™ Alloy, ATI 201™ Alloy, ATI 22™ Alloy, ATI 235™ Alloy, ATI 2535™ Alloy, ATI 2550™ Alloy, ATI 35N LoTi™ Alloy, ATI 35N™ Alloy, ATI 400™ Alloy, ATI 42™ Alloy, ATI 500 ZB™ Alloy, ATI 520™ Alloy, ATI 600™ Alloy, ATI 617™ Alloy, ATI 6230™ Alloy, ATI 625 Lo-Fe™ Alloy, ATI 625™ Alloy, ATI 690™ Alloy, ATI 700™ Alloy, ATI 706™ Alloy, ATI 718-OP® Alloy, ATI 718Plus® Alloy, ATI 718™ Alloy, ATI 720™ Alloy, ATI 800™ Alloy, ATI 80A™ Alloy, ATI 825™ Alloy, ATI 901™ Alloy, ATI 903™ Alloy, ATI 909™ Alloy, ATI 925™ Alloy, ATI A286™ Alloy, ATI ASTROLOY™ Alloy, ATI C-263™ Alloy, ATI C-276™ Alloy, ATI Gator Waspaloy* Alloy ( * a Trademark of Pratt & Whitney), ATI GTD-222™ Alloy, ATI HB-2™ Alloy, ATI HG™ Alloy, ATI HN™ Alloy, ATI HS™ Alloy, ATI HX™ Alloy, ATI K-500™ Alloy, ATI L-605™ Alloy, ATI M-252™ Alloy, ATI MOLY PERMALLOY™ Alloy, ATI N-90™ Alloy, ATI P-31™ Alloy, ATI PE-16™ Alloy, ATI R26™ Alloy, ATI Super Waspaloy* Alloy (* a Trademark of Pratt & Whitney), ATI W-722™ Alloy, ATI X-750™ Alloy, ATI X-751™ Alloy, ATI X-849™ Alloy, Rene 41™ Alloy, Rene 65™ Alloy, RENE 88 DT Alloy, RR1000* (* a Trademark of Rolls-Royce plc), TJA-1537® Hi-Carb Alloy, TJA-1537® Lo-Carb Alloy, Waspaloy* Alloy (* a Trademark of Pratt & Whitney) Recommended use of the chemical and restrictions on use Recommended Use Nickel alloy product manufacture. Uses advised against Details of the supplier of the safety data sheet Emergency telephone number Emergency Telephone Chemtrec: 1-800-424-9300 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). This product is an article and, as such, does not present a hazard to human health by inhalation or ingestion. Acute toxicity - Oral Category 4 Respiratory sensitization Category 1B Skin sensitization Category 1 Carcinogenicity Category 1B Reproductive toxicity Category 2 Specific target organ toxicity (repeated exposure)Category 1 Chronic aquatic toxicity Category 4 Label elements Emergency Overview Manufacturer Address ATI, 1000 Six PPG Place, Pittsburgh, PA 15222 USA Page 1 / 11 North America; English _____________________________________________________________________________________________ SM001 Nickel-Base Alloys Revision Date 03-Aug-2018 Precautionary Statements - Prevention Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wear protective gloves If skin irritation or rash occurs: Get medical advice/attention If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information When product is subjected to welding, burning, melting, sawing, brazing, grinding, buffing, polishing, or other similar heat-generating processes, the following potentially hazardous airborne particles and/or fumes may be generated:: Titanium dioxide an IARC Group 2B carcinogen, Hexavalent Chromium (Chromium VI) may cause lung, nasal, and/or sinus cancer, Zinc, copper, magnesium, or cadmium fumes may cause metal fumes fever, Soluble molybdenum compounds such as molybdenum trioxide may cause lung irritation. 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Non-powder forms of A905L™ Alloy, ATI 10242™ Alloy, ATI 120™ Alloy, Rene 88DT, ATI 188™ Alloy, ATI 200™ Alloy, ATI 201™ Alloy, ATI 22™ Alloy, ATI 235™ Alloy, ATI 2535™ Alloy, ATI 2550™ Alloy, ATI 35N LoTi™ Alloy, ATI 35N™ Alloy, ATI 400™ Alloy, ATI 42™ Alloy, ATI 500 ZB™ Alloy, ATI 520™ Alloy, ATI 600™ Alloy, ATI 617™ Alloy, ATI 6230™ Alloy, ATI 625 Lo-Fe™ Alloy, ATI 625™ Alloy, ATI 690™ Alloy, ATI 700™ Alloy, ATI 706™ Alloy, ATI 718-OP® Alloy, ATI 718Plus® Alloy, ATI 718™ Alloy, ATI 720™ Alloy, ATI 800™ Alloy, ATI 80A™ Alloy, ATI 825™ Alloy, ATI 901™ Alloy, ATI 903™ Alloy, ATI 909™ Alloy, ATI 925™ Alloy, ATI A286™ Alloy, ATI ASTROLOY™ Alloy, ATI C-263™ Alloy, ATI C-276™ Alloy, ATI Gator Waspaloy* Alloy ( * a Trademark of Pratt & Whitney), ATI GTD-222™ Alloy, ATI HB-2™ Alloy, ATI HG™ Alloy, ATI HN™ Alloy, ATI HS™ Alloy, ATI HX™ Alloy, ATI K-500™ Alloy, ATI L-605™ Alloy, ATI M-252™ Alloy, ATI MOLY PERMALLOY™ Alloy, ATI N-90™ Alloy, ATI P-31™ Alloy, ATI PE-16™ Alloy, ATI R26™ Alloy, ATI Super Waspaloy* Alloy (* a Trademark of Pratt & Whitney), ATI W-722™ Alloy, ATI X-750™ Alloy, ATI X-751™ Alloy, ATI X-849™ Alloy, Rene 41™ Alloy, Rene 65™ Danger Hazard statements Harmful if swallowed May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause an allergic skin reaction May cause cancer Suspected of damaging fertility or the unborn child Causes damage to the respiratory tract through prolonged or repeated exposure if inhaled May cause long lasting harmful effects to aquatic life Appearance Various massive product forms Physical state Solid Odor Odorless Page 2 / 11 North America; English _____________________________________________________________________________________________ SM001 Nickel-Base Alloys Revision Date 03-Aug-2018 Alloy, RENE 88 DT Alloy, RR1000* (* a Trademark of Rolls-Royce plc), TJA-1537® Hi-Carb Alloy, TJA-1537® Lo-Carb Alloy, Waspaloy* Alloy (* a Trademark of Pratt & Whitney). Chemical Name CAS No.Weight-% Nickel 7440-02-0 30 - 100 Iron 7439-89-6 0 - 42 Chromium 7440-47-3 0 - 35 Cobalt 7440-48-4 0 - 35 Copper 7440-50-8 0 - 35 Molybdenum 7439-98-7 0 - 26 Tungsten 7440-33-7 0 - 16 Niobium (Columbium)7440-03-1 0 - 6 Tantalum 7440-25-7 0 - 5 Titanium 7440-32-6 0 - 5 Aluminum 7429-90-5 0 - 5 Manganese 7439-96-5 0 - 5 . 4. FIRST AID MEASURES First aid measures Eye contact In the case of particles coming in contact with eyes during processing, treat as with any foreign object. Skin Contact In the case of skin irritation or allergic reactions see a physician. Inhalation If excessive amounts of smoke, fume, or particulate are inhaled during processing, remove to fresh air and consult a qualified health professional. Ingestion Not an expected route of exposure. Most important symptoms and effects, both acute and delayed Symptoms May cause allergic skin reaction. May cause acute gastrointestinal effects if swallowed. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Product not flammable in the form as distributed, flammable as finely divided particles or pieces resulting from processing of this product. Isolate large fires and allow to burn out. Smother small fires with salt (NaCl) or class D dry powder fire extinguisher. Unsuitable extinguishing media Do not spray water on burning metal as an explosion may occur. This explosive characteristic is caused by the hydrogen and steam generated by the reaction of water with the burning material. Specific hazards arising from the chemical Intense heat. Very fine, high surface area material resulting from grinding, buffing, polishing, or similar processes of this product may ignite spontaneously at room temperature. WARNING: Fine particles resulting from grinding, buffing, polishing, or similar processes of this product may form combustible dust-air mixtures. Keep particles away from all ignition sources including heat, sparks, and flame. Prevent dust accumulations to minimize combustible dust hazard. Hazardous combustion productsTitanium dioxide an IARC Group 2B carcinogen, Hexavalent Chromium (Chromium VI) may cause lung, nasal, and/or sinus cancer, Zinc, copper, magnesium, or cadmium fumes may cause metal fumes fever, Soluble molybdenum compounds such as molybdenum trioxide may cause lung irritation. Page 3 / 11 North America; English _____________________________________________________________________________________________ SM001 Nickel-Base Alloys Revision Date 03-Aug-2018 Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. For emergency responders Use personal protective equipment as required. Environmental precautions Environmental precautions Not applicable to massive product. Methods and material for containment and cleaning up Methods for containment Not applicable to massive product. Methods for cleaning up Not applicable to massive product. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Very fine, high surface area material resulting from grinding, buffing, polishing, or similar processes of this product may ignite spontaneously at room temperature. WARNING: Fine particles resulting from grinding, buffing, polishing, or similar processes of this product may form combustible dust-air mixtures. Keep particles away from all ignition sources including heat, sparks, and flame. Prevent dust accumulations to minimize combustible dust hazard. Conditions for safe storage, including any incompatibilities Storage Conditions Keep chips, turnings, dust, and other small particles away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Dissolves in hydrofluoric acid. Ignites in the presence of fluorine. When heated above 200°C, reacts exothermically with the following: Chlorine, bromine, halocarbons, carbon tetrachloride, carbon tetrafluoride, and freon. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Chemical Name ACGIH TLV OSHA PEL Nickel 7440-02-0 TWA: 1.5 mg/m3 inhalable fraction TWA: 1 mg/m3 Iron 7439-89-6 -- Copper 7440-50-8 TWA: 0.2 mg/m3 fume TWA: 1 mg/m3 Cu dust and mist TWA: 0.1 mg/m3 fume TWA: 1 mg/m3 dust and mist Cobalt 7440-48-4 TWA: 0.02 mg/m3 TWA: 0.02 mg/m3 Co TWA: 0.1 mg/m3 dust and fume Chromium 7440-47-3 TWA: 0.5 mg/m3 TWA: 1 mg/m3 Molybdenum 7439-98-7 TWA: 10 mg/m3 inhalable fraction TWA: 3 mg/m3 respirable fraction - Tungsten STEL: 10 mg/m3 STEL: 10 mg/m3 W (vacated) STEL: 10 mg/m3 (vacated) STEL: Page 4 / 11 North America; English _____________________________________________________________________________________________ SM001 Nickel-Base Alloys Revision Date 03-Aug-2018 7440-33-7 TWA: 5 mg/m3 TWA: 5 mg/m3 W 10 mg/m3 W Niobium (Columbium) 7440-03-1 -- Titanium 7440-32-6 -- Tantalum 7440-25-7 -TWA: 5 mg/m3 Manganese 7439-96-5 TWA: 0.02 mg/m3 respirable fraction TWA: 0.1 mg/m3 inhalable fraction TWA: 0.02 mg/m3 Mn TWA: 0.1 mg/m3 Mn (vacated) STEL: 3 mg/m3 fume (vacated) Ceiling: 5 mg/m3 Ceiling: 5 mg/m3 fume Ceiling: 5 mg/m3 Mn Aluminum 7429-90-5 TWA: 1 mg/m3 respirable fraction TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction Appropriate engineering controls Engineering Controls Avoid generation of uncontrolled particles. Individual protection measures, such as personal protective equipment Eye/face protection When airborne particles may be present, appropriate eye protection is recommended. For example, tight-fitting goggles, foam-lined safety glasses or other protective equipment that shield the eyes from particles. Skin and body protection Fire/flame resistant/retardant clothing may be appropriate during hot work with the product. Cut-resistant gloves and/or protective clothing may be appropriate when sharp surfaces are present. Respiratory protection When particulates/fumes/gases are generated and if exposure limits are exceeded or irritation is experienced, proper approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Solid Appearance Various massive product forms Odor Odorless Color metallic Grey silver Odor threshold Not applicable Property Values Remarks • Method pH -Not applicable Melting point/freezing point 1420 - 1450 °C / 2590 - 2650 °F Boiling point / boiling range - Flash point - Evaporation rate -Not applicable Flammability (solid, gas)-Product not flammable in the form as distributed, flammable as finely divided particles or pieces resulting from processing of this product Flammability Limit in Air Upper flammability limit:- Lower flammability limit:- Vapor pressure -Not applicable Vapor density -Not applicable Specific Gravity 7-9 Water solubility Insoluble Solubility in other solvents -Not applicable Partition coefficient -Not applicable Autoignition temperature -Not applicable Page 5 / 11 North America; English _____________________________________________________________________________________________ SM001 Nickel-Base Alloys Revision Date 03-Aug-2018 Explosive properties Not applicable Oxidizing properties Not applicable Other Information Softening point - Molecular weight - VOC Content (%)Not applicable Density - Bulk density - 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization Hazardous polymerization does not occur. Conditions to avoid Dust formation and dust accumulation. Incompatible materials Dissolves in hydrofluoric acid. Ignites in the presence of fluorine. When heated above 200°C, reacts exothermically with the following: Chlorine, bromine, halocarbons, carbon tetrachloride, carbon tetrafluoride, and freon. Hazardous Decomposition Products When product is subjected to welding, burning, melting, sawing, brazing, grinding, buffing, polishing, or other similar heat-generating processes, the following potentially hazardous airborne particles and/or fumes may be generated:: Titanium dioxide an IARC Group 2B carcinogen, Hexavalent Chromium (Chromium VI) may cause lung, nasal, and/or sinus cancer, Soluble molybdenum compounds such as molybdenum trioxide may cause lung irritation. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Not an expected route of exposure for product in massive form. Eye contact Not an expected route of exposure for product in massive form. Skin Contact May cause sensitization by skin contact. Ingestion Not an expected route of exposure for product in massive form. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Nickel 7440-02-0 > 9000 mg/kg bw -> 10.2 mg/L Iron 7439-89-6 98,600 mg/kg bw -> 0.25 mg/L Copper 7440-50-8 481 mg/kg bw >2000 mg/kg bw >5.11 mg/L Cobalt 550 mg/kg bw >2000 mg/kg bw <0.05 mg/L Decomposition temperature -Not applicable Kinematic viscosity -Not applicable Dynamic viscosity -Not applicable Not applicable Page 6 / 11 North America; English _____________________________________________________________________________________________ SM001 Nickel-Base Alloys Revision Date 03-Aug-2018 7440-48-4 Chromium 7440-47-3 > 3400 mg/kg bw -> 5.41 mg/L Molybdenum 7439-98-7 > 2000 mg/kg bw > 2000 mg/kg bw > 5.10 mg/L Tungsten 7440-33-7 > 2000 mg/kg bw > 2000 mg/kg bw > 5.4 mg/L Niobium (Columbium) 7440-03-1 > 10,000 mg/kg bw > 2000 mg/kg bw - Titanium 7440-32-6 > 5000 mg/kg bw -- Tantalum 7440-25-7 > 2000 mg/kg bw > 2000 mg/kg bw > 5.18 mg/L Manganese 7439-96-5 >2000 mg/kg bw ->5.14 mg/L Aluminum 7429-90-5 15,900 mg/kg bw -> 1 mg/L Information on toxicological effects Symptoms May cause sensitization by skin contact. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause acute gastrointestinal effects if swallowed. Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity Harmful if swallowed. Cobalt-containing powders may be fatal if inhaled. Skin corrosion/irritation Product not classified. Serious eye damage/eye irritation Product not classified. Sensitization May cause sensitization by skin contact. Cobalt-containing alloys may cause sensitization by inhalation. Germ cell mutagenicity Product not classified. Carcinogenicity May cause cancer by inhalation. Chemical Name ACGIH IARC NTP OSHA Nickel 7440-02-0 Group 1 Group 2B Known Reasonably Anticipated X Cobalt 7440-48-4 A3 Group 2A Group 2B Known X Chromium 7440-47-3 Group 3 Reproductive toxicity Possible risk of impaired fertility. STOT - single exposure Product not classified. STOT - repeated exposure Causes disorder and damage to the: Respiratory System. Aspiration hazard Product not classified. 12. ECOLOGICAL INFORMATION Ecotoxicity This product as shipped is classified for aquatic chronic toxicity. Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Nickel 7440-02-0 NOEC/EC10 values range from 12.3 µg/l for Scenedesmus accuminatus to 425 µg/l for Pseudokirchneriella subcapitata. The 96h LC50s values range from 0.4 mg Ni/L for Pimephales promelas to 320 mg Ni/L for Brachydanio rerio. The 30 min EC50 of nickel for activated sludge was 33 mg Ni/L. The 48h LC50s values range from 0.013 mg Ni/L for Ceriodaphnia dubia to 4970 mg Ni/L for Daphnia magna. Iron 7439-89-6 -The 96 h LC50 of 50% iron oxide black in water to Danio rerio was greater than 10,000 mg/L. The 3 h EC50 of iron oxide for activated sludge was greater than 10,000 mg/L. The 48 h EC50 of iron oxide to Daphnia magna was greater than 100 mg/L. Page 7 / 11 North America; English _____________________________________________________________________________________________ SM001 Nickel-Base Alloys Revision Date 03-Aug-2018 Copper 7440-50-8 The 72 h EC50 values of copper chloride to Pseudokirchneriella subcapitata ranged between 30 µg/L (pH 7.02, hardness 250 mg/L CaCO3, DOC 1.95 mg/L) and 824 µg/L (pH 6.22, hardness 100 mg/L CaCO3, DOC 15.8 mg/L). The 96-hr LC50 for Pimephales promelas exposed to Copper sulfate ranged from 256.2 to 38.4 ug/L with water hardness increasing from 45 to 255.7 mg/L. The 24 h NOEC of copper chloride for activated sludge ranged from 0.32 to 0.64 mg of Cu/L. The 48 h LC50 values for Daphnia magna exposed to copper in natural water ranged between 33.8 µg/L (pH 6.1, hardness 12.4 mg/L CaCO3, DOC 2.34 mg/L) and 792 µg/L (pH 7.35, hardness 139.7 mg/L CaCO3, DOC 22.8 mg/L). Cobalt 7440-48-4 The 72 h EC50 of cobalt dichloride to Pseudokirchneriella subcapitata was 144 ug of Co/L. The 96h LC50 of cobalt dichloride ranged from 1.5 mg Co/L for Oncorhynchus mykiss to 85 mg Co/L for Danio rerio. The 3 h EC50 of cobalt dichloride for activated sludge was 120 mg of Co/L. The 48 h LC50 of cobalt dichloride ranged from 0.61 mg Co/L for Ceriodaphnia dubia tested in soft, DOM-free water to >1800mg Co/L for Tubifex tubifex in very hard water. Chromium 7440-47-3 ---- Molybdenum 7439-98-7 The 72 h EC50 of sodium molybdate dihydrate to Pseudokirchneriella subcapitata was 362.9 mg of Mo/L. The 96 h LC50 of sodium molybdate dihydrate to Pimephales promelas was 644.2 mg/L The 3 h EC50 of molybdenum trioxide for activated sludge was 820 mg/L. The 48 h LC50 of sodium molybdate dihydrate to Ceriodaphnia dubia was 1,015 mg/L. The 48 h LC50 of sodium molybdate dihydrate to Daphnia magna was greater than 1,727.8 mg/L. Tungsten 7440-33-7 The 72 h EC50 of sodium tungstate to Pseudokirchnerella subcapitata was 31.0 mg of W/L. The 96 h LC50 of sodium tungstate to Danio rerio was greater than 106 mg of W/L. The 30 min EC50 of sodium tungstate for activated sludge were greater than 1000 mg/L. The 48 h EC50 of sodium tungstate to Daphnia magna was greater than 96 mg of W/L. Niobium (Columbium) 7440-03-1 ---- Titanium 7440-32-6 The 72 h EC50 of titanium dioxide to Pseudokirchnerella subcapitata was 61 mg of TiO2/L. The 96 h LC50 of titanium dioxide to Cyprinodon variegatus was greater than 10,000 mg of TiO2/L. The 96 h LC50 of titanium dioxide to Pimephales promelas was greater than 1,000 mg of TiO2/L . The 3 h EC50 of titanium dioxide for activated sludge were greater than 1000 mg/L. The 48 h EC50 of titanium dioxide to Daphnia Magna was greater than 1000 mg of TiO2/L. Tantalum 7440-25-7 ---- Manganese 7439-96-5 The 72 h EC50 of manganese to Desmodesmus subspicatus was 2.8 mg of Mn/L. The 96 h LC50 of manganese to Oncorhynchus mykiss was greater than 3.6 mg of Mn/L The 3 h EC50 of manganese for activated sludge was greater than 1000 mg/L. The 48 h EC50 of manganese to Daphnia magna was greater than 1.6 mg/L. Aluminum 7429-90-5 The 96-h EC50 values for reduction of biomass of Pseudokirchneriella subcapitata in AAP-Medium at pH 6, 7, and 8 were estimated as 20.1, 5.4, and 150.6 µg/L, respectively, for dissolved Al. The 96 h LC50 of aluminum to Oncorhynchus mykiss was 7.4 mg of Al/L at pH 6.5 and 14.6 mg of Al/L at pH 7.5 -The 48-hr LC50 for Ceriodaphnia dubia exposed to Aluminium chloride increased from 0.72 to greater than 99.6 mg/L with water hardness increasing from 25 to 200 mg/L. Persistence and degradability . Bioaccumulation . Other adverse effects This product as shipped is not classified for acute environmental endpoints. However, when subjected to sawing or grinding, particles may be generated that are classified for aquatic acute toxicity. Page 8 / 11 13. DISPOSAL CONSIDERATIONS North America; English _____________________________________________________________________________________________ SM001 Nickel-Base Alloys Revision Date 03-Aug-2018 Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging None anticipated. Chemical Name RCRA - D Series Wastes Chromium 7440-47-3 5.0 mg/L regulatory level This product contains one or more substances that are listed with the State of California as a hazardous waste. 14. TRANSPORT INFORMATION DOT Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Not Listed AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name CAS No.Weight-%SARA 313 - Threshold Values % Nickel - 7440-02-0 7440-02-0 30 - 100 0.1 Copper - 7440-50-8 7440-50-8 0 - 35 1.0 Cobalt - 7440-48-4 7440-48-4 0 - 35 0.1 Chromium - 7440-47-3 7440-47-3 0 - 35 1.0 Manganese - 7439-96-5 7439-96-5 0 - 5 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No Reactive Hazard No Page 9 / 11 CWA (Clean Water Act) North America; English _____________________________________________________________________________________________ SM001 Nickel-Base Alloys Revision Date 03-Aug-2018 This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Nickel 7440-02-0 X X Copper 7440-50-8 X X Chromium 7440-47-3 X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs Nickel 7440-02-0 100 lb Copper 7440-50-8 5000 lb Chromium 7440-47-3 5000 lb US State Regulations California Proposition 65 This product contains the Proposition 65 chemicals listed below. Proposition 65 warning label available at ATImetals.com. Chemical Name California Proposition 65 Nickel - 7440-02-0 Carcinogen Cobalt - 7440-48-4 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Nickel 7440-02-0 X X X Copper 7440-50-8 X X X Cobalt 7440-48-4 X X X Chromium 7440-47-3 X X X Molybdenum 7439-98-7 X X X Tungsten 7440-33-7 X X X Titanium 7440-32-6 X Tantalum 7440-25-7 X X X Manganese 7439-96-5 X X X Aluminum 7429-90-5 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable 16. OTHER INFORMATION NFPA Health hazards 1 Flammability 0 Instability 0 Physical and Chemical Properties - HMIS Health hazards 2*Flammability 0 Physical hazards 0 Personal protection X Page 10 / 11 North America; English _____________________________________________________________________________________________ SM001 Nickel-Base Alloys Revision Date 03-Aug-2018 Chronic Hazard Star Legend * = Chronic Health Hazard Issue Date 28-May-2015 Revision Date 03-Aug-2018 Revision Note Updated Section(s): 2, 5, 9, 12, 15 Note: The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Additional information available from: Safety data sheets and labels available at ATImetals.com Page 11 / 11 North America; English