HomeMy WebLinkAboutSDS - Stainless Steel - ATISAFETY DATA SHEET
Issue Date 28-May-2015 Revision Date 04-Sep-2018 Version
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name Stainless Steel
Other means of identification
Product Code FRP008
Synonyms Stainless Steel: ATI 20™, ATI 20-20+Nb™, ATI 201™, ATI 219™, 21-6-9, ATI 40 Stainless
Steel, XM-11, ATI 301™, ATI 302™, ATI 303™, ATI 304™, ATI 305™, ATI 309™, ATI
310™, ATI 316™, ATI 317™, ATI 321™, ATI 255™ DUPLEX, ATI 332™, ATI 334™, ATI
347™, ATI 348™, AM 350®, AM 355™, ATI 403™, ATI Ohmaloy® 30, ATI Ohmaloy® 40,
ATI Ohmaloy®, ATI 409 HP™, ATI 409 Cb™, ATI 410™, ATI 412™, Type 415, ATI 416™,
ATI 420™, ATI 430™, ATI 433™, Type 434, Type 436, ATI 439™, ATI 439 HP™, XM-8,
Type 441, 18-0, ATI 18CrCb, ATI 441 HP™, ATI 444™, 18-2, ATI 468™, ATI 15-5™, ATI
17-4™, ATI 17-7™, ATI 15-7™, ATI JS700® ALLOY, ATI 800™ ALLOY, ATI 825™
ALLOY, Type 840, ATI E-BRITE® 26-1, ASTM XM 27, ATI 2205™ DUPLEX; 318, ATI
2205™ DUPLEX; 322, ATI 201LN™, Type 301L, ATI 304 DA™, Type 304H, ATI 304L™,
374L, Type 304LN, Type 304N, Type 309H, ATI 309S™, 398, Type 309Si, Type 310Cb,
Type 310H, Type 310L, ATI 310S™, Type 310Si, ATI 316L™, 376, ATI 316LN™, ATI
316Ti™, ATI 317L™, ATI 317LMN™, 317 LX, 317 LXN, 317 XN, Type 321H, Type 410
MOD, Type 410HC, ATI 410S™, ATI 418 SPL™, Type 420HC, ALLEGHENY Type 425
Modified, ATI 436S™, ATI 440A™, ATI 440C™, ATI 800 AT™ ALLOY, ATI 800 H™
ALLOY, ATI 904L™, ATI 610™, ATI 611™, ATI 13-8Mo™, ATI 13-8 SuperTough®, ATI
13-8 STAINLESS STEEL, ASTM Type XM-13, ATI 2003® DUPLEX, ATI 20-25+Nb alloy,
AL 29-4C®, ATI 332Mo® alloy, ATI 334Mo® alloy, ATI 201HP™, ATI 33, XM-29, ATI
4565™, ATI 50™, 22-13-5, XM-19, ATI 60™, 21800, AL-6XN® ALLOY, AL-6XN Plus®
ALLOY, A286 Altemp®, PC1017, Sea Cure ® 26-3-3, Zeron® 100, 22-4-9, 21-11N,
HOLDER BLOCK STEEL, MAXEL 400 SUPER, AL-6X, AL 404, Type 405, Type 446, AL
29-4C®, AL 29-4, AL 29-4-2, 14-4 FERRITIC, AL 453, AL 466, ALTEMP ® ALLOY STEEL,
19-9-DL, Type 302B, ATI 409 Cb™, Type 409Ni, ATI 430Ti™, ALLEGHENY EDRO
441MOD1, ALLEGHENY CRUCIBLE 441MOD2, TOOL STEEL D2T, CSM-21 STAINLESS
STEEL, ULTRACHEM STAINLESS STEEL, RA85H STEEL, 385, ZeCor™, RA 330 ™ ,
ATI304B7 P/M™ BOR7
Recommended use of the chemical and restrictions on use
Recommended Use Stainless steel product manufacture.
Uses advised against
Details of the supplier of the safety data sheet
Emergency telephone number
Emergency Telephone Chemtrec: 1-800-424-9300
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). This product is
an article and, as such, does not present a hazard to human health by inhalation or ingestion.
Skin sensitization Category 1
Carcinogenicity Category 1B
Manufacturer Address
ATI, 1000 Six PPG Place, Pittsburgh, PA
15222 USA
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Specific target organ toxicity (repeated exposure)Category 1
Label elements
Emergency Overview
Precautionary Statements - Prevention
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wear protective gloves
If skin irritation or rash occurs: Get medical advice/attention
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
When product is subjected to welding, burning, melting, sawing, brazing, grinding, buffing, polishing, or other similar
heat-generating processes, the following potentially hazardous airborne particles and/or fumes may be generated:: Zinc, copper,
magnesium, or cadmium fumes may cause metal fume fever, Titanium dioxide an IARC Group 2B carcinogen, Hexavalent
Chromium (Chromium VI) may cause lung, nasal, and/or sinus cancer, Vanadium pentoxide (V2O5) affects eyes, skin, respiratory
system, Soluble molybdenum compounds such as molybdenum trioxide may cause lung irritation.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Synonyms Stainless Steel: ATI 20™, ATI 20-20+Nb™, ATI 201™, ATI 219™, 21-6-9, ATI 40 Stainless
Steel, XM-11, ATI 301™, ATI 302™, ATI 303™, ATI 304™, ATI 305™, ATI 309™, ATI
310™, ATI 316™, ATI 317™, ATI 321™, ATI 255™ DUPLEX, ATI 332™, ATI 334™, ATI
347™, ATI 348™, AM 350®, AM 355™, ATI 403™, ATI Ohmaloy® 30, ATI Ohmaloy® 40,
ATI Ohmaloy®, ATI 409 HP™, ATI 409 Cb™, ATI 410™, ATI 412™, Type 415, ATI 416™,
ATI 420™, ATI 430™, ATI 433™, Type 434, Type 436, ATI 439™, ATI 439 HP™, XM-8,
Type 441, 18-0, ATI 18CrCb, ATI 441 HP™, ATI 444™, 18-2, ATI 468™, ATI 15-5™, ATI
17-4™, ATI 17-7™, ATI 15-7™, ATI JS700® ALLOY, ATI 800™ ALLOY, ATI 825™
ALLOY, Type 840, ATI E-BRITE® 26-1, ASTM XM 27, ATI 2205™ DUPLEX; 318, ATI
2205™ DUPLEX; 322, ATI 201LN™, Type 301L, ATI 304 DA™, Type 304H, ATI 304L™,
374L, Type 304LN, Type 304N, Type 309H, ATI 309S™, 398, Type 309Si, Type 310Cb,
Type 310H, Type 310L, ATI 310S™, Type 310Si, ATI 316L™, 376, ATI 316LN™, ATI
316Ti™, ATI 317L™, ATI 317LMN™, 317 LX, 317 LXN, 317 XN, Type 321H, Type 410
MOD, Type 410HC, ATI 410S™, ATI 418 SPL™, Type 420HC, ALLEGHENY Type 425
Danger
Hazard statements
May cause cancer
May cause an allergic skin reaction
Causes damage to the respiratory tract through prolonged or repeated exposure if inhaled
Appearance Various massive product
forms
Physical state Solid Odor Odorless
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Modified, ATI 436S™, ATI 440A™, ATI 440C™, ATI 800 AT™ ALLOY, ATI 800 H™
ALLOY, ATI 904L™, ATI 610™, ATI 611™, ATI 13-8Mo™, ATI 13-8 SuperTough®, ATI
13-8 STAINLESS STEEL, ASTM Type XM-13, ATI 2003® DUPLEX, ATI 20-25+Nb alloy,
AL 29-4C®, ATI 332Mo® alloy, ATI 334Mo® alloy, ATI 201HP™, ATI 33, XM-29, ATI
4565™, ATI 50™, 22-13-5, XM-19, ATI 60™, 21800, AL-6XN® ALLOY, AL-6XN Plus®
ALLOY, A286 Altemp®, PC1017, Sea Cure ® 26-3-3, Zeron® 100, 22-4-9, 21-11N,
HOLDER BLOCK STEEL, MAXEL 400 SUPER, AL-6X, AL 404, Type 405, Type 446, AL
29-4C®, AL 29-4, AL 29-4-2, 14-4 FERRITIC, AL 453, AL 466, ALTEMP ® ALLOY STEEL,
19-9-DL, Type 302B, ATI 409 Cb™, Type 409Ni, ATI 430Ti™, ALLEGHENY EDRO
441MOD1, ALLEGHENY CRUCIBLE 441MOD2, TOOL STEEL D2T, CSM-21 STAINLESS
STEEL, ULTRACHEM STAINLESS STEEL, RA85H STEEL, 385, ZeCor™, RA 330 ™ ,
ATI304B7 P/M™ BOR7.
Chemical Name CAS No.Weight-%
Iron 7439-89-6 <90
Nickel 7440-02-0 0-46
Chromium 7440-47-3 10-30
Manganese 7439-96-5 0-10
Molybdenum 7439-98-7 0-7.0
Silicon 7440-21-3 0-6.5
Aluminum 7429-90-5 0-4.0
Copper 7440-50-8 0-4.0
Tungsten 7440-33-7 0-2.5
Titanium 7440-32-6 0-2.4
Boron 7440-42-8 0-2.25
Vanadium 7440-62-2 0-1.1
Tantalum 7440-25-7 0-1.0
Niobium (Columbium)7440-03-1 0-1.0
Cobalt 7440-48-4 0-0.5
.
4. FIRST AID MEASURES
First aid measures
Eye contact In the case of particles coming in contact with eyes during processing, treat as with any
foreign object.
Skin Contact In the case of skin allergic reactions see a physician.
Inhalation If excessive amounts of smoke, fume, or particulate are inhaled during processing, remove
to fresh air and consult a qualified health professional.
Ingestion Not an expected route of exposure.
Most important symptoms and effects, both acute and delayed
Symptoms May cause allergic skin reaction.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Product not flammable in the form as distributed, flammable as finely divided particles or pieces resulting from processing of this
product. Isolate large fires and allow to burn out. Smother small fires with salt (NaCl) or class D dry powder fire extinguisher.
Unsuitable extinguishing media Do not spray water on burning metal as an explosion may occur. This explosive
characteristic is caused by the hydrogen and steam generated by the reaction of water with
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FRP008 Stainless Steel Revision Date 04-Sep-2018
the burning material.
Specific hazards arising from the chemical
Intense heat. Very fine, high surface area material resulting from grinding, buffing, polishing, or similar processes of this product
may ignite spontaneously at room temperature. WARNING: Fine particles resulting from grinding, buffing, polishing, or similar
processes of this product may form combustible dust-air mixtures. Keep particles away from all ignition sources including heat,
sparks, and flame. Prevent dust accumulations to minimize combustible dust hazard.
Hazardous combustion productsTitanium dioxide an IARC Group 2B carcinogen. Hexavalent Chromium (Chromium VI) may
cause lung, nasal, and/or sinus cancer. Vanadium pentoxide (V2O5) affects eyes, skin,
respiratory system. Zinc, copper, magnesium, or cadmium fumes may cause metal fume
fever. Soluble molybdenum compounds such as molybdenum trioxide may cause lung
irritation.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Protective equipment and precautions for firefighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment as required.
For emergency responders Use personal protective equipment as required.
Environmental precautions
Environmental precautions Not applicable to massive product.
Methods and material for containment and cleaning up
Methods for containment Not applicable to massive product.
Methods for cleaning up Not applicable to massive product.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Very fine, high surface area material resulting from grinding, buffing, polishing, or similar
processes of this product may ignite spontaneously at room temperature. WARNING: Fine
particles resulting from grinding, buffing, polishing, or similar processes of this product may
form combustible dust-air mixtures. Keep particles away from all ignition sources including
heat, sparks, and flame. Prevent dust accumulations to minimize combustible dust hazard.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep chips, turnings, dust, and other small particles away from heat, sparks, flame and
other sources of ignition (i.e., pilot lights, electric motors and static electricity).
Incompatible materials Dissolves in hydrofluoric acid. Ignites in the presence of fluorine. When heated above
200°C, reacts exothermically with the following: Chlorine, bromine, halocarbons, carbon
tetrachloride, carbon tetrafluoride, and freon.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
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Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL
Iron
7439-89-6
--
Nickel
7440-02-0
TWA: 1.5 mg/m3 inhalable fraction TWA: 1 mg/m3
Chromium
7440-47-3
TWA: 0.5 mg/m3 TWA: 1 mg/m3
Manganese
7439-96-5
TWA: 0.02 mg/m3 respirable fraction
TWA: 0.1 mg/m3 inhalable fraction TWA:
0.02 mg/m3 Mn
TWA: 0.1 mg/m3 Mn
(vacated) STEL: 3 mg/m3 fume
(vacated) Ceiling: 5 mg/m3
Ceiling: 5 mg/m3 fume Ceiling: 5 mg/m3 Mn
Molybdenum
7439-98-7
TWA: 10 mg/m3 inhalable fraction
TWA: 3 mg/m3 respirable fraction
-
Silicon
7440-21-3
-TWA: 15 mg/m3 total dust
TWA: 5 mg/m3 respirable fraction
Copper
7440-50-8
TWA: 0.2 mg/m3 fume TWA: 1 mg/m3 Cu
dust and mist
TWA: 0.1 mg/m3 fume
TWA: 1 mg/m3 dust and mist
Aluminum
7429-90-5
TWA: 1 mg/m3 respirable fraction TWA: 15 mg/m3 total dust
TWA: 5 mg/m3 respirable fraction
Tungsten
7440-33-7
STEL: 10 mg/m3 STEL: 10 mg/m3 W
TWA: 5 mg/m3 TWA: 5 mg/m3 W
(vacated) STEL: 10 mg/m3 (vacated) STEL:
10 mg/m3 W
Titanium
7440-32-6
--
Boron
7440-42-8
--
Vanadium
7440-62-2
-Ceiling: 0.5 mg/m3 V2O5 respirable dust
Ceiling: 0.1 mg/m3 V2O5 fume
Tantalum
7440-25-7
-TWA: 5 mg/m3
Niobium (Columbium)
7440-03-1
--
Cobalt
7440-48-4
TWA: 0.02 mg/m3 TWA: 0.02 mg/m3 Co TWA: 0.1 mg/m3 dust and fume
Appropriate engineering controls
Engineering Controls Avoid generation of uncontrolled particles.
Individual protection measures, such as personal protective equipment
Eye/face protection When airborne particles may be present, appropriate eye protection is recommended. For
example, tight-fitting goggles, foam-lined safety glasses or other protective equipment that
shield the eyes from particles.
Skin and body protection Fire/flame resistant/retardant clothing may be appropriate during hot work with the product.
Cut-resistant gloves and/or protective clothing may be appropriate when sharp surfaces are
present.
Respiratory protection When particulates/fumes/gases are generated and if exposure limits are exceeded or
irritation is experienced, proper approved respiratory protection should be worn.
Positive-pressure supplied air respirators may be required for high airborne contaminant
concentrations. Respiratory protection must be provided in accordance with current local
regulations.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state Solid
Appearance Various massive product forms Odor Odorless
Color metallic, gray or silver Odor threshold Not applicable
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Explosive properties Not applicable
Oxidizing properties Not applicable
Other Information
Softening point -
Molecular weight -
VOC Content (%)Not applicable
Density -
Bulk density -
10. STABILITY AND REACTIVITY
Reactivity
Chemical stability
Stable under normal conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous polymerization Hazardous polymerization does not occur.
Conditions to avoid
Dust formation and dust accumulation.
Incompatible materials
Dissolves in hydrofluoric acid. Ignites in the presence of fluorine. When heated above 200°C, reacts exothermically with the
following: Chlorine, bromine, halocarbons, carbon tetrachloride, carbon tetrafluoride, and freon.
Hazardous Decomposition Products
When product is subjected to welding, burning, melting, sawing, brazing, grinding, buffing, polishing, or other similar
heat-generating processes, the following potentially hazardous airborne particles and/or fumes may be generated:: Titanium
dioxide an IARC Group 2B carcinogen. Hexavalent Chromium (Chromium VI) may cause lung, nasal, and/or sinus cancer.
Vanadium pentoxide (V2O5) affects eyes, skin, respiratory system. Soluble molybdenum compounds such as molybdenum trioxide
may cause lung irritation.
Property Values Remarks • Method
pH -
Melting point/freezing point 1430-1540 °C / 2600-2800 °F
Boiling point / boiling range -
Flash point -
Evaporation rate -Not applicable
Flammability (solid, gas)-Product not flammable in the form as distributed,
flammable as finely divided particles or pieces
resulting from processing of this product
Flammability Limit in Air
Upper flammability limit:-
Lower flammability limit:-
Vapor pressure -Not applicable
Vapor density -Not applicable
Specific Gravity 7-9
Water solubility Insoluble
Solubility in other solvents -Not applicable
Partition coefficient -Not applicable
Autoignition temperature -Not applicable
Decomposition temperature -Not applicable
Kinematic viscosity -Not applicable
Dynamic viscosity -Not applicable
Not applicable
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation Not an expected route of exposure for product in massive form.
Eye contact Not an expected route of exposure for product in massive form.
Skin Contact Nickel or Cobalt containing alloys may cause sensitization by skin contact.
Ingestion Not an expected route of exposure for product in massive form.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Iron
7439-89-6
98,600 mg/kg bw -> 0.25 mg/L
Nickel
7440-02-0
> 9000 mg/kg bw -> 10.2 mg/L
Chromium
7440-47-3
> 3400 mg/kg bw -> 5.41 mg/L
Manganese
7439-96-5
>2000 mg/kg bw ->5.14 mg/L
Molybdenum
7439-98-7
> 2000 mg/kg bw > 2000 mg/kg bw > 5.10 mg/L
Silicon
7440-21-3
> 5000 mg/kg bw > 5000 mg/kg bw > 2.08 mg/L
Copper
7440-50-8
481 mg/kg bw >2000 mg/kg bw >5.11 mg/L
Aluminum
7429-90-5
15,900 mg/kg bw -> 1 mg/L
Tungsten
7440-33-7
> 2000 mg/kg bw > 2000 mg/kg bw > 5.4 mg/L
Titanium
7440-32-6
> 5000 mg/kg bw --
Boron
7440-42-8
> 2000 mg/kg bw -> 5.08 mg/L
Vanadium
7440-62-2
> 2000 mg/kg bw --
Tantalum
7440-25-7
> 2000 mg/kg bw > 2000 mg/kg bw > 5.18 mg/L
Niobium (Columbium)
7440-03-1
> 10,000 mg/kg bw > 2000 mg/kg bw -
Cobalt
7440-48-4
550 mg/kg bw >2000 mg/kg bw <0.05 mg/L
Information on toxicological effects
Symptoms Nickel or Cobalt containing alloys may cause sensitization by skin contact.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Acute toxicity Product not classified.
Skin corrosion/irritation Product not classified.
Serious eye damage/eye irritation Product not classified.
Sensitization Nickel or Cobalt containing alloys may cause sensitization by skin contact.
Cobalt-containing alloys may cause sensitization by inhalation.
Germ cell mutagenicity Product not classified.
Carcinogenicity May cause cancer by inhalation.
Chemical Name ACGIH IARC NTP OSHA
Nickel
7440-02-0
Group 1
Group 2B
Known
Reasonably Anticipated
X
Chromium
7440-47-3
Group 3
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Cobalt
7440-48-4
A3 Group 2A
Group 2B
Known X
Reproductive toxicity Product not classified.
STOT - single exposure Product not classified.
STOT - repeated exposure Causes disorder and damage to the: Respiratory System.
Aspiration hazard Product not classified.
12. ECOLOGICAL INFORMATION
Ecotoxicity
This product as shipped is not classified for aquatic toxicity.
Chemical Name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
Iron
7439-89-6
-The 96 h LC50 of 50% iron
oxide black in water to Danio
rerio was greater than
10,000 mg/L.
The 3 h EC50 of iron oxide
for activated sludge was
greater than 10,000 mg/L.
The 48 h EC50 of iron oxide
to Daphnia magna was
greater than 100 mg/L.
Nickel
7440-02-0
NOEC/EC10 values range
from 12.3 µg/l for
Scenedesmus accuminatus
to 425 µg/l for
Pseudokirchneriella
subcapitata.
The 96h LC50s values range
from 0.4 mg Ni/L for
Pimephales promelas to 320
mg Ni/L for Brachydanio
rerio.
The 30 min EC50 of nickel
for activated sludge was 33
mg Ni/L.
The 48h LC50s values range
from 0.013 mg Ni/L for
Ceriodaphnia dubia to 4970
mg Ni/L for Daphnia magna.
Chromium
7440-47-3
----
Manganese
7439-96-5
The 72 h EC50 of
manganese to
Desmodesmus subspicatus
was 2.8 mg of Mn/L.
The 96 h LC50 of
manganese to
Oncorhynchus mykiss was
greater than 3.6 mg of Mn/L
The 3 h EC50 of manganese
for activated sludge was
greater than 1000 mg/L.
The 48 h EC50 of
manganese to Daphnia
magna was greater than 1.6
mg/L.
Molybdenum
7439-98-7
The 72 h EC50 of sodium
molybdate dihydrate to
Pseudokirchneriella
subcapitata was 362.9 mg of
Mo/L.
The 96 h LC50 of sodium
molybdate dihydrate to
Pimephales promelas was
644.2 mg/L
The 3 h EC50 of
molybdenum trioxide for
activated sludge was 820
mg/L.
The 48 h LC50 of sodium
molybdate dihydrate to
Ceriodaphnia dubia was
1,015 mg/L.
The 48 h LC50 of sodium
molybdate dihydrate to
Daphnia magna was greater
than 1,727.8 mg/L.
Silicon
7440-21-3
The 72 h EC50 of sodium
metasilicate pentahydrate to
Pseudokirchnerella
subcapitata was greater than
250 mg/L.
---
Copper
7440-50-8
The 72 h EC50 values of
copper chloride to
Pseudokirchneriella
subcapitata ranged between
30 µg/L (pH 7.02, hardness
250 mg/L CaCO3, DOC 1.95
mg/L) and 824 µg/L (pH
6.22, hardness 100 mg/L
CaCO3, DOC 15.8 mg/L).
The 96-hr LC50 for
Pimephales promelas
exposed to Copper sulfate
ranged from 256.2 to 38.4
ug/L with water hardness
increasing from 45 to 255.7
mg/L.
The 24 h NOEC of copper
chloride for activated sludge
ranged from 0.32 to 0.64 mg
of Cu/L.
The 48 h LC50 values for
Daphnia magna exposed to
copper in natural water
ranged between 33.8 µg/L
(pH 6.1, hardness 12.4 mg/L
CaCO3, DOC 2.34 mg/L)
and 792 µg/L (pH 7.35,
hardness 139.7 mg/L
CaCO3, DOC 22.8 mg/L).
Aluminum
7429-90-5
The 96-h EC50 values for
reduction of biomass of
Pseudokirchneriella
subcapitata in AAP-Medium
at pH 6, 7, and 8 were
estimated as 20.1, 5.4, and
150.6 µg/L, respectively, for
dissolved Al.
The 96 h LC50 of aluminum
to Oncorhynchus mykiss
was 7.4 mg of Al/L at pH 6.5
and 14.6 mg of Al/L at pH
7.5
-The 48-hr LC50 for
Ceriodaphnia dubia exposed
to Aluminium chloride
increased from 0.72 to
greater than 99.6 mg/L with
water hardness increasing
from 25 to 200 mg/L.
Tungsten
7440-33-7
The 72 h EC50 of sodium
tungstate to
Pseudokirchnerella
subcapitata was 31.0 mg of
W/L.
The 96 h LC50 of sodium
tungstate to Danio rerio was
greater than 106 mg of W/L.
The 30 min EC50 of sodium
tungstate for activated
sludge were greater than
1000 mg/L.
The 48 h EC50 of sodium
tungstate to Daphnia magna
was greater than 96 mg of
W/L.
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Titanium
7440-32-6
The 72 h EC50 of titanium
dioxide to
Pseudokirchnerella
subcapitata was 61 mg of
TiO2/L.
The 96 h LC50 of titanium
dioxide to Cyprinodon
variegatus was greater than
10,000 mg of TiO2/L.
The 96 h LC50 of titanium
dioxide to Pimephales
promelas was greater than
1,000 mg of TiO2/L .
The 3 h EC50 of titanium
dioxide for activated sludge
were greater than 1000
mg/L.
The 48 h EC50 of titanium
dioxide to Daphnia Magna
was greater than 1000 mg of
TiO2/L.
Boron
7440-42-8
The 72-h EC50 value for
reduction of biomass of
Pseudokirchneriella
subcapitata exposed to Boric
acid at pH 7.5 to 8.3 was
40.2 mg/L.
The 96-hr LC50 for
Pimephales promelas
exposed to Boric acid
(82%)/borax (18%) mixture
was 79.7 mg/L with water
hardness of 91 mg/L and
water pH of 8.0.
The 3 h NOEC of boric acid
for activated sludge ranged
from 17.5 to 20 mg/L.
The 48-hr LC50 for
Ceriodaphnia dubia exposed
to Boric acid/borax mixture
ranged from 91 to 165 mg/L
with pH ranging from 6.7 to
8.4.
Vanadium
7440-62-2
The 72 h EC50 of vanadium
pentoxide to Desmodesmus
subspicatus was 2,907 ug of
V/L.
The 96 h LC50 of vanadium
pentoxide to Pimephales
promelas was 1,850 ug of
V/L .
The 3 h EC50 of sodium
metavanadate for activated
sludge was greater than 100
mg/L.
The 48 h EC50 of sodium
vanadate to Daphnia magna
was 2,661 ug of V/L.
Tantalum
7440-25-7
----
Niobium (Columbium)
7440-03-1
----
Cobalt
7440-48-4
The 72 h EC50 of cobalt
dichloride to
Pseudokirchneriella
subcapitata was 144 ug of
Co/L.
The 96h LC50 of cobalt
dichloride ranged from 1.5
mg Co/L for Oncorhynchus
mykiss to 85 mg Co/L for
Danio rerio.
The 3 h EC50 of cobalt
dichloride for activated
sludge was 120 mg of Co/L.
The 48 h LC50 of cobalt
dichloride ranged from 0.61
mg Co/L for Ceriodaphnia
dubia tested in soft,
DOM-free water to >1800mg
Co/L for Tubifex tubifex in
very hard water.
Persistence and degradability
.
Bioaccumulation
.
Other adverse effects This product as shipped is not classified for environmental endpoints. However, when
subjected to sawing or grinding, particles may be generated that are classified for aquatic
chronic toxicity.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging None anticipated.
Chemical Name RCRA - D Series Wastes
Chromium
7440-47-3
5.0 mg/L regulatory level
This product contains one or more substances that are listed with the State of California as a hazardous waste.
14. TRANSPORT INFORMATION
DOT Not regulated
Page 9 / 11
15. REGULATORY INFORMATION
North America; English
_____________________________________________________________________________________________
FRP008 Stainless Steel Revision Date 04-Sep-2018
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Not Listed
AICS Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
Chromium (Cr)
Chemical Name CAS No.Weight-%SARA 313 - Threshold Values %
Nickel - 7440-02-0 7440-02-0 0-46 0.1
Chromium - 7440-47-3 7440-47-3 10-30 1.0
Manganese - 7439-96-5 7439-96-5 0-10 1.0
Copper - 7440-50-8 7440-50-8 0-4.0 1.0
Cobalt - 7440-48-4 7440-48-4 0-0.5 0.1
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Chemical Name CWA - Reportable
Quantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
Nickel
7440-02-0
X X
Chromium
7440-47-3
X X
Copper
7440-50-8
X X
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs
Nickel
7440-02-0
100 lb
Chromium
7440-47-3
5000 lb
Copper 5000 lb
Page 10 / 11
North America; English
_____________________________________________________________________________________________
FRP008 Stainless Steel Revision Date 04-Sep-2018
7440-50-8
US State Regulations
California Proposition 65
This product contains the Proposition 65 chemicals listed below. Proposition 65 warning label available at ATImetals.com.
Chemical Name California Proposition 65
Nickel - 7440-02-0 Carcinogen
Cobalt - 7440-48-4 Carcinogen
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Nickel
7440-02-0
X X X
Chromium
7440-47-3
X X X
Manganese
7439-96-5
X X X
Molybdenum
7439-98-7
X X X
Silicon
7440-21-3
X X X
Copper
7440-50-8
X X X
Aluminum
7429-90-5
X X X
Tungsten
7440-33-7
X X X
Titanium
7440-32-6
X
Vanadium
7440-62-2
X X X
Tantalum
7440-25-7
X X X
Cobalt
7440-48-4
X X X
U.S. EPA Label Information
EPA Pesticide Registration Number Not applicable
16. OTHER INFORMATION
Chronic Hazard Star Legend * = Chronic Health Hazard
Issue Date 28-May-2015
Revision Date 04-Sep-2018
Revision Note
Updated Section(s): 2, 3, 4, 5, 9, 11, 12, 15
Note:
The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
Additional information available
from:
Safety data sheets and labels available at ATImetals.com
NFPA Health hazards 1 Flammability 0 Instability 0 Physical and Chemical
Properties -
HMIS Health hazards 2*Flammability 0 Physical hazards 0
Page 11 / 11
Personal protection X
North America; English